EFEKTIVITAS ELEKTROKOAGULASI DENGAN ELEKTRODA Al, Zn, DAN Ni DALAM MENGOLAH LIMBAH CAIR INDUSTRI KERTAS: PENGURANGAN COD DAN TURBIDITAS
Keywords:
degradation, electrocoagulation, wastewaterAbstract
The aim of this research is to assess the effectiveness of electrocoagulation in reducing COD (Chemical Oxygen Demand) and turbidity in wastewater from the paper industry using Al, Zn, and Ni electrodes. Wastewater from the paper industry was treated with electrocoagulation using Al, Zn, and Ni electrodes at a voltage of 10 volts. Contact times tested were 30, 45, 60, and 90 minutes. Measured parameters included COD, pH, and turbidity both before and after treatment. The initial wastewater conditions showed a COD value of 2950 mg/L, pH 8.48, and turbidity of 315.4 NTU. The Al electrode performed the best in reducing COD and turbidity. At a 90-minute contact time, the Al electrode successfully reduced COD to 970 mg/L and turbidity to 155 NTU with a final pH of 7.3. Meanwhile, the Zn and Ni electrodes resulted in COD reductions of 970 mg/L and 910 mg/L, as well as turbidity values of 155 NTU and 125 NTU. Electrocoagulation with the Al electrode proved to be more effective in treating wastewater from the paper industry compared to the Zn and Ni electrodes. The results of this study demonstrate the significant potential of electrocoagulation, especially with the Al electrode, as an environmentally friendly and effective method for treating wastewater from the paper industry. The adoption of this technique could reduce wastewater treatment costs by improving efficiency and reducing chemical consumptionReferences
Al Kholif, M., Rohmah, M., Nurhayati, I., Adi Walujo, D., & Dian Majid, D. (2022). Penurunan Beban Pencemar Rumah Potong Hewan (RPH) Menggunakan Sistem Biofilter Anaerob. Jurnal Sains & Teknologi Lingkungan, 14(2), 100–113. Retrieved from https://journal.uii.ac.id/JSTL/article/view/23979
Chen, G. (2004). Electrochemical technologies in wastewater treatment. Separation and Purification Technology, 38(1), 11–41. https://doi.org/https://doi.org/10.1016/j.seppur.2003.10.006
Dian, M., & Il-Kyu, K. (2018). Degradation of Toluene by Liquid Ferrate(VI) and Solid Ferrate(VI) in Aqueous Phase. Journal of Environmental Engineering, 144(9), 4018093 1-8. https://doi.org/10.1061/(ASCE)EE.1943-7870.0001440
Gavrilescu, D., Puitel, A., Dutuc, G., & Craciun, G. (2012). Environmental impact of pulp and paper mills. Environmental Engineering and Management Journal, 11, 81–86. https://doi.org/10.30638/eemj.2012.012
Gomes, J. A. G., Daida, P., Kesmez, M., Weir, M., Moreno, H., Parga, J. R., … Cocke, D. L. (2007). Arsenic removal by electrocoagulation using combined Al–Fe electrode system and characterization of products. Journal of Hazardous Materials, 139(2), 220–231. https://doi.org/https://doi.org/10.1016/j.jhazmat.2005.11.108
Holt, P. K., Barton, G. W., & Mitchell, C. A. (2005). The future for electrocoagulation as a localised water treatment technology. Chemosphere, 59(3), 355–367. https://doi.org/https://doi.org/10.1016/j.chemosphere.2004.10.023
Igwegbe, C., Onukwuli, O., O. Ighalo, J., Umembamalu, C. J., & Adeniyi, A. (2021). Comparative analysis on the electrochemical reduction of colour, COD and turbidity from municipal solid waste leachate using aluminium, iron and hybrid electrodes. Sustainable Water Resources Management, 7. https://doi.org/10.1007/s40899-021-00524-w
Kumar, D., & Sharma, C. (2022). Paper industry wastewater treatment by electrocoagulation and aspect of sludge management. Journal of Cleaner Production, 360, 131970. https://doi.org/https://doi.org/10.1016/j.jclepro.2022.131970
Laksono, F. B., Majid, D., & Prabowo, A. R. (2022). System and eco-material design based on slow-release ferrate(vi) combined with ultrasound for ballast water treatment. 12(1), 401–408. https://doi.org/doi:10.1515/eng-2022-0042
Ma, X., Ge, P., Wang, L., Sun, W., Bu, Y., Sun, M., & Yang, Y. (2023). The Recycling of Spent Lithium-Ion Batteries: Crucial Flotation for the Separation of Cathode and Anode Materials. Molecules, Vol. 28. https://doi.org/10.3390/molecules28104081
Majid, D., Kim, I.-K., Laksono, F. B., & Prabowo, A. R. (2021). Oxidative Degradation of Hazardous Benzene Derivatives by Ferrate(VI): Effect of Initial pH, Molar Ratio and Temperature. Toxics, 9(12), 1–10. https://doi.org/10.3390/toxics9120327
Majid, D., & Kim, I. (2019). Sintesis dan Aplikasi Ferrat sebagai Green Chemical dalam Pengolahan Limbah. SNHRP, 184–189.
Majid, D., Prabowo, A. R., Al-Kholif, M., & Sugito, S. (2019). Sintesis Ferrat sebagai Pendegradasi Senyawa Turunan Benzena. JPSE (Journal of Physical Science and Engineering), 3(2), 70–75. https://doi.org/10.17977/um024v3i22018p070
Moreira, F. (2017). Electrochemical advanced oxidation processes: A review on their application to synthetic and real wastewaters. Applied Catalysis B: Environmental, Vol. 202, pp. 217–261. https://doi.org/10.1016/j.apcatb.2016.08.037
Mouedhen, G., Feki, M., Wery, M. D. P., & Ayedi, H. F. (2008). Behavior of aluminum electrodes in electrocoagulation process. Journal of Hazardous Materials, 150(1), 124–135. https://doi.org/https://doi.org/10.1016/j.jhazmat.2007.04.090
Negash, A., Tibebe, D., Mulugeta, M., & Kassa, Y. (2023). A study of basic and reactive dyes removal from synthetic and industrial wastewater by electrocoagulation process. South African Journal of Chemical Engineering, 46, 122–131. https://doi.org/https://doi.org/10.1016/j.sajce.2023.07.015
Nurhayati, I., Vigiani, S., & Majid, D. (2020). Penurunan Kadar Besi (Fe), Kromium (Cr), COD dan BOD Limbah Cair Laboratorium dengan Pengenceran, Kougulasi dan Adsorbsi. Ecotrophic, 14(1)(June), 74–87.
Sahoo, D., & Anandhi, A. (2023). Conceptualizing turbidity for aquatic ecosystems in the context of sustainable development goals. Environmental Science: Advances, 2(9), 1220–1234. https://doi.org/10.1039/D2VA00327A
Shannon, M. A., Bohn, P. W., Elimelech, M., Georgiadis, J. G., Mariñas, B. J., & Mayes, A. M. (2008). Science and technology for water purification in the coming decades. Nature, 452(7185), 301–310. https://doi.org/10.1038/nature06599
Tuye, I. W., Sutrisno, J., & Majid, D. (2023). Potensi salvinia molesta dan pistia stratiotes dalam penurunan kadar fosfat, BOD, dan COD pada limbah cair laundry. WAKTU: Jurnal Teknik UNIPA, 21(02). https://doi.org/10.36456/waktu.v21i02.7727